1: 5 type and 2:17 type sintered Samarium Cobalt magnets are called as the first generation and second generation of rare earth permanent magnets. 2:17 type is developed based on 1:5 type. Neodymium magnets dominated the market of rare earth permanent magnets since its inception and then Samarium Cobalt magnets are marginalized seriously due to magnetic performance, complex processing technologies, and costs. But in fact, sintered Samarium Cobalt magnet is still playing an irreplaceable role in high-temperature and high temperature stability applications which is not possible for Neodymium magnets. The research of high-performance sintered Samarium Cobalt magnets has never stopped, thus complex multistage heating treatment and microstructure control promoted magnetic performance of Samarium Cobalt magnets to an extreme. United States Department of Defense demanded that enhance the maximum operating temperature of sintered Samarium Cobalt magnet to the 500 degrees Celsius from 300 degrees Celsius to meet the new applications in aerospace in 1997. In the meanwhile, some higher high-end applications like travelling wave tube and internal device also asked reversible temperature coefficient of sintered Samarium Cobalt magnets should have small enough absolute value. Therefore, TbCu7-type structure Sm2Co7-based magnets emerged and gained widely concern.
Manufacturing Process of Sintered Samarium Cobalt Magnets
Magnetic Properties of Sintered Samarium Cobalt Magnets
Material | Grade | Remanence Br | Coercivity Hcb | Intrinsic Coercivity Hcj | Max. Energy Product (BH)max | Curie Temp Tc | Max. Oper Tem. Tw | Temp. Coeff. of Br | Temp. Coeff. of Hcj | ||||
T | kGs | kA/m | KOe | kA | kOe | kJ/m3 | MGOe | ℃ | ℃ | %/℃ | %/℃ | ||
SmCo5 | RECo5-16S | 0.79-0.84 | 7.9-8.4 | 620-660 | 7.8-8.3 | ≥1830 | ≥23.0 | 118-135 | 15-17 | 750 | 250 | -0.035 | -0.28 |
RECo5–18S | 0.84-0.89 | 8.4-8.9 | 660-700 | 8.3-8.8 | ≥1830 | ≥23.0 | 135-151 | 17-19 | 750 | 250 | -0.040 | -0.28 | |
RECo5–20S | 0.89-0.93 | 8.9-9.3 | 684-732 | 8.6-9.2 | ≥1830 | ≥23.0 | 150-167 | 19-21 | 750 | 250 | -0.045 | -0.28 | |
RECo5–22S | 0.92-0.96 | 9.2-9.6 | 710-756 | 8.9-9.5 | ≥1830 | ≥23.0 | 167-183 | 21-23 | 750 | 250 | -0.045 | -0.28 | |
RECo5–24S | 0.96-1.00 | 9.6-10.0 | 740-788 | 9.3-9.9 | ≥1830 | ≥23.0 | 183-199 | 23-25 | 750 | 250 | -0.045 | -0.28 | |
(SmGd)Co5 | LTC-10 | 0.62-0.66 | 6.2-6.6 | 485-517 | 6.1-6.5 | ≥1830 | ≥23.0 | 75-88 | 9.5-11.0 | 750 | 300 | 20-100℃: +0.0156 100-200℃: +0.0087 200-300℃: +0.0007 | – |
Sm2(Co,Fe,Cu,Zr)17 | RE2Co17-24H | 0.95-1.02 | 9.5-10.2 | 692-764 | 8.7-9.6 | ≥1990 | ≥25.0 | 175-191 | 22-24 | 800 | 350 | -0.025 | -0.20 |
RE2Co17-26H | 1.02-1.05 | 10.2-10.5 | 740-788 | 9.4-10.0 | ≥1990 | ≥25.0 | 191-207 | 24-26 | 800 | 350 | -0.030 | -0.20 | |
RE2Co17-28H | 1.03-1.08 | 10.3-10.8 | 756-812 | 9.5-10.2 | ≥1990 | ≥25.0 | 207-220 | 26-28 | 800 | 350 | -0.035 | -0.20 | |
RE2Co17-30H | 1.08-1.10 | 10.8-11.0 | 788-835 | 9.9-10.5 | ≥1990 | ≥25.0 | 220-240 | 28-30 | 800 | 350 | -0.035 | -0.20 | |
RE2Co17-32H | 1.10-1.13 | 11.0-11.3 | 812-860 | 10.2-10.8 | ≥1990 | ≥25.0 | 230-255 | 29-32 | 800 | 350 | -0.035 | -0.20 | |
RE2Co17-22 | 0.93-0.97 | 9.3-9.7 | 676-740 | 8.5-9.3 | ≥1433 | ≥18.0 | 160-183 | 20-23 | 800 | 300 | -0.020 | -0.20 | |
RE2Co17-24 | 0.95-1.02 | 9.5-10.2 | 692-764 | 8.7-9.6 | ≥1433 | ≥18.0 | 175-191 | 22-24 | 800 | 300 | -0.025 | -0.20 | |
RE2Co17-26 | 1.02-1.05 | 10.2-10.5 | 748-796 | 9.4-10.0 | ≥1433 | ≥18.0 | 191-207 | 24-26 | 800 | 300 | -0.030 | -0.20 | |
RE2Co17-28 | 1.03-1.08 | 10.3-10.8 | 756-812 | 9.5-10.2 | ≥1433 | ≥18.0 | 207-220 | 26-28 | 800 | 300 | -0.035 | -0.20 | |
RE2Co17-30 | 1.08-1.10 | 10.8-11.0 | 788-835 | 9.9-10.5 | ≥1433 | ≥18.0 | 220-240 | 28-30 | 800 | 300 | -0.035 | -0.20 | |
RE2Co17-32 | 1.10-1.13 | 11.0-11.3 | 812-860 | 10.2-10.8 | ≥1433 | ≥18.0 | 230-255 | 29-32 | 800 | 300 | -0.035 | -0.20 | |
RE2Co17-26M | 1.02-1.05 | 10.2-10.5 | 676-780 | 8.5-9.8 | 955-1433 | 12-18 | 191-207 | 24-26 | 800 | 300 | -0.035 | -0.20 | |
RE2Co17-28M | 1.03-1.08 | 10.3-10.8 | 676-796 | 8.5-10.0 | 955-1433 | 12-18 | 207-220 | 26-28 | 800 | 300 | -0.035 | -0.20 | |
RE2Co17-30M | 1.08-1.10 | 10.8-11.0 | 676-835 | 8.5-10.5 | 955-1433 | 12-18 | 220-240 | 28-30 | 800 | 300 | -0.035 | -0.20 | |
RE2Co17-32M | 1.10-1.13 | 11.0-11.3 | 676-852 | 8.5-10.7 | 955-1433 | 12-18 | 230-255 | 29-32 | 800 | 300 | -0.035 | -0.20 | |
RE2Co17-24L | 0.95-1.02 | 9.5-10.2 | 541-716 | 6.8-9.0 | 636-955 | 8-12 | 175-191 | 22-24 | 800 | 250 | -0.025 | -0.20 | |
RE2Co17-26L | 1.02-1.05 | 10.2-10.5 | 541-748 | 6.8-9.4 | 636-955 | 8-12 | 191-207 | 24-26 | 800 | 250 | -0.035 | -0.20 | |
RE2Co17-28L | 1.03-1.08 | 10.3-10.8 | 541-764 | 6.8-9.6 | 636-955 | 8-12 | 207-220 | 26-28 | 800 | 250 | -0.035 | -0.20 | |
RE2Co17-30L | 1.08-1.15 | 10.8-11.5 | 541-796 | 6.8-10.0 | 636-955 | 8-12 | 220-240 | 28-30 | 800 | 250 | -0.035 | -0.20 | |
RE2Co17-32L | 1.10-1.15 | 11.0-11.5 | 541-812 | 6.9-10.2 | 636-955 | 8-12 | 230-255 | 29-32 | 800 | 250 | -0.035 | -0.20 | |
(Sm,Er)2(Co,Tm)17 | LTC-16 | 0.81-0.85 | 8.1-8.5 | 605-669 | 7.6-8.4 | ≥1592 | ≥20 | 117-127 | 14-16 | 840 | 300 | -50-20℃: +0.005 20-100℃: -0.008 100-200℃: -0.008 200-300℃: -0.011 | – |
LTC-18 | 0.85-0.90 | 8.5-9.0 | 629-708 | 7.9-8.9 | ≥1592 | ≥20 | 127-143 | 16-18 | 840 | 300 | |||
LTC-20 | 0.90-0.94 | 9.0-9.4 | 661-732 | 8.3-9.2 | ≥1592 | ≥20 | 143-159 | 18-20 | 840 | 300 | |||
LTC-22 | 0.94-0.97 | 9.4-9.7 | 685-740 | 8.6-9.3 | ≥1592 | ≥20 | 159-175 | 20-22 | 840 | 300 | |||
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Physical Properties of Sintered Samarium Cobalt Magnets
Parameters | Unit | SmCo5 | Sm2Co17 |
Density / ρ | g/cm3 | 8.1-8.5 | 8.3-8.5 |
Vickers Hardness | HV | 450-500 | 500-600 |
Compressive Strength | MPa | 420-680 | 700-830 |
Electrical Resistivity | Ω·cm | (5-6)x10-5 | (8-9)x10-5 |
Coeff. of Thermal Expansion | 10-6/K |
C⊥: 13 C∥: 6 |
C⊥: 11 C∥: 8 |
Performance Difference between Different Magnetic Material
Material | (BH)max MGOe | Hcj kOe | Temper. Coeff. of Br %/℃ | Max. Operating Temper ℃ | Anti-corrosition Capability |
SmCo5 | 16-25 | 15-25 | -0.05 | 200-250 | Good |
Sm2Co17 | 22-32 | 6-30 | -0.03 | 250-350 | Good |
Nd2Fe14B | 26-52 | 12-33 | -0.11 | 80-230 | Bad |
Ferrite | 3.0-4.5 | 3.0-4.5 | -0.19 | 200-300 | Good |
AlNiCo | 5-10 | 1.0-1.8 | -0.03 | 450-500 | Excellent |
Notes:
- Actually, sintered Samarium Cobalt magnets are not suitable to be structure part due to inherent brittleness.
- SmCo5 magnets are relatively easier to machine compared to Sm2Co17 magnets.
- Customers who purchase non-magnetize Samarium Cobalt magnets should equip appropriate magnetizing equipment to ensure saturated magnetization.
- SDM also serve coated Samarium Cobalt magnets to use under harsh environments.